New Interphase Improves Performance, Safety of Lithium Metal Batteries

Penn State
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Penn State researchers have developed a new solid-electrolyte interphase (SEI) to improve the performance and safety of lithium metal batteries.

High-energy-density lithium metal batteries have been touted as the future of electric vehicles, smartphones, and drones.

However one major issue halting their progress is the stability of their SEIs. The culprit over here is a salt layer found on the surface of the battery’s lithium electrode which insulates it and conducts lithium ions.

“This layer is very important and is naturally formed by the reaction between the lithium and the electrolyte in the battery,” says Penn State professor Donghai Wang. “But it doesn’t behave very well, which causes a lot of problems.”

According to the researchers, degradation of the SEI results in dendrites that negatively affect a battery’s performance and safety.

“This is why lithium metal batteries don’t last longer – the interphase grows and it’s not stable,” says Wang.

In order to remedy this, the Penn State team has used a polymer composite to create a much better SEI.

Led by chemistry doctoral student Yue Gao, the enhanced SEI is a reactive polymer composite consisting of polymeric lithium salt, lithium fluoride nanoparticles, and graphene oxide sheets.

The novel construction of this battery component has thin layers of these materials, which is where Thomas E. Mallouk, Evan Pugh University Professor of Chemistry, lent his expertise.

“There is a lot of molecular-level control that is needed to achieve a stable lithium interface,” Mallouk said. “The polymer that Yue and Donghai designed reacts to make a claw-like bond to the lithium metal surface. It gives the lithium surface what it wants in a passive way so that it doesn’t react with the molecules in the electrolyte. The nanosheets in the composite act as a mechanical barrier to prevent dendrites from forming from the lithium metal.”

Using both chemistry and engineering design, the collaboration between fields enabled the technology to control the lithium surface at the atomic scale.

“When we engineer batteries, we don’t necessarily think like chemists, all the way down to the molecular level, but that’s what we needed to do here,” said Mallouk.

The reactive polymer also helps decrease the weight and manufacturing cost, which could in turn lead to the wide spread adoption of lithium metal batteries.

New Interphase Improves Performance, Safety of Lithium Metal Batteries